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Photocatalytic reductive sulfonylation and 1,2-alkyl migration cascades of vinyl cyclobutanols: A synthesis of beta-sulfonated cyclopentanones
- Kim, Joo Hee;
- Kim, Dae Young
Citations
WEB OF SCIENCE
22Citations
SCOPUS
23초록
A photoredox strategy to access beta-sulfonated cyclopentanones from the reaction of vinyl cyclobutanols with sulfonyl chlorides is described. This reaction employs the inexpensive and easily accessible sulfonyl chlorides as a sulfonyl radical source. The present synthetic protocol is a convenient way to prepare beta-sulfonated cyclopentanones.
키워드
beta-sulfonated cyclopentanones; photoredox process; semipinacol-type rearrangement; sulfonyl chlorides; vinyl cyclobutanols; VISIBLE-LIGHT PHOTOREDOX; ASYMMETRIC-SYNTHESIS; RING EXPANSION; KETO ACIDS; METAL-FREE; CYCLIZATION; SEQUENCES; TETRAHYDROQUINOLINES; ALKENES; OXIDATION
- 제목
- Photocatalytic reductive sulfonylation and 1,2-alkyl migration cascades of vinyl cyclobutanols: A synthesis of beta-sulfonated cyclopentanones
- 저자
- Kim, Joo Hee; Kim, Dae Young
- 발행일
- 2020-01-17
- 유형
- Article
- 권
- 50
- 호
- 2
- 페이지
- 207 ~ 216
- 언어
- ENG
- 출판사
- Marcel Dekker Inc.
- 발행국가
- 미국
- 분량
- 10 페이지
- ISSN
- E 1532-2432
P 0039-7911