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Visible Light Photoredox-Catalyzed Arylative Ring Expansion of 1-(1-Arylvinyl)cyclobutanol Derivatives
- Kwon, Su Jin;
- Kim, Dae Young
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81초록
A visible light mediated photocatalytic arylation/ring expansion of alkenylcyclobutanols has been developed. This approach provides a mild and operationally simple access to the synthesis of functionalized cyclic ketones from the coupling reaction of alkenylcyclobutanols with aryldiazonium salts.
키워드
Visible Light Photoredox; Arylative Ring Expansion; 1‑(1-Arylvinyl)cyclobutanol Derivatives; CONCOMITANT 1,2-ARYL MIGRATION; ALPHA,ALPHA-DIARYL ALLYLIC ALCOHOLS; ARYL DIAZONIUM SALTS; ONE-POT SYNTHESIS; ELECTRON-DEFICIENT ALKENES; METAL-FREE CONDITIONS; C-H ARYLATION; 1,5-HYDRIDE TRANSFER/CYCLIZATION; ASYMMETRIC-SYNTHESIS; UNACTIVATED ALKENES
- 제목
- Visible Light Photoredox-Catalyzed Arylative Ring Expansion of 1-(1-Arylvinyl)cyclobutanol Derivatives
- 저자
- Kwon, Su Jin; Kim, Dae Young
- 발행일
- 2016-09-16
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 18
- 호
- 18
- 페이지
- 4562 ~ 4565
- 언어
- ENG
- 출판사
- American Chemical Society
- 발행국가
- 미국
- 분량
- 4 페이지
- ISSN
- E 1523-7052
P 1523-7060