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Visible light photoredox-catalyzed phosphorylation of α-bromostyrenes: a mild synthesis of β-ketophosphine oxides
- Kim, Rabin;
- Kim, Dae Young
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2초록
Visible light-mediated photocatalytic phosphorylation of alpha-bromostyrenes is described. The beta-ketophosphine oxide derivatives were conveniently synthesized from alpha-bromostyrene derivatives, which are useful synthetic intermediates, using an inexpensive organic photocatalyst, Eosin Y.{Graphical Abstract}
키워드
alpha-bromostyrenes; beta-ketophosphine oxides; photoredox reaction; phosphinoyl radical; H-PHOSPHINE OXIDES; ONE-POT SYNTHESIS; ASYMMETRIC-SYNTHESIS; AEROBIC OXYPHOSPHORYLATION; RADICAL OXYPHOSPHORYLATION; RING EXPANSION; ALKENYL ACIDS; ALKYNES; BOND; PHOSPHONATES
- 제목
- Visible light photoredox-catalyzed phosphorylation of α-bromostyrenes: a mild synthesis of β-ketophosphine oxides
- 저자
- Kim, Rabin; Kim, Dae Young
- 발행일
- 2024-02
- 유형
- Article
- 권
- 199
- 호
- 2
- 페이지
- 162 ~ 168