Visible light photoredox-catalyzed phosphorylation of α-bromostyrenes: a mild synthesis of β-ketophosphine oxides

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초록

Visible light-mediated photocatalytic phosphorylation of alpha-bromostyrenes is described. The beta-ketophosphine oxide derivatives were conveniently synthesized from alpha-bromostyrene derivatives, which are useful synthetic intermediates, using an inexpensive organic photocatalyst, Eosin Y.{Graphical Abstract}

키워드

alpha-bromostyrenes; beta-ketophosphine oxides; photoredox reaction; phosphinoyl radical; H-PHOSPHINE OXIDES; ONE-POT SYNTHESIS; ASYMMETRIC-SYNTHESIS; AEROBIC OXYPHOSPHORYLATION; RADICAL OXYPHOSPHORYLATION; RING EXPANSION; ALKENYL ACIDS; ALKYNES; BOND; PHOSPHONATES
제목
Visible light photoredox-catalyzed phosphorylation of α-bromostyrenes: a mild synthesis of β-ketophosphine oxides
저자
Kim, Rabin; Kim, Dae Young
DOI
10.1080/10426507.2023.2281476
발행일
2024-02
유형
Article
저널명
Phosphorus, Sulfur and Silicon and the Related Elements
권
199
호
2
페이지
162 ~ 168