Electrochemical bromolactonization of alkenoic acids with carbon tetrabromide: Synthesis of bromomethylated gamma-lactones

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초록

Electrochemical radical bromination and cyclization sequences of alkenoic acids developed in this study. This approach is environmental-friendly by using carbon tetrabromide as a bromine radical precursor. The electrochemical protocol offers a facile way to prepare bromomethylated gamma-lactones derivatives in moderate to high yields. [GRAPHICS] .

키워드

Alkenoic acidsbromolactonizationelectrochemical reactiongamma-lactonesC-H FUNCTIONALIZATIONMIGRATION SEQUENCESELECTROCATALYTIC APPROACHANODIC-OXIDATIONRING EXPANSIONBROMIDEQUINOXALIN-2(1H)-ONESCYCLOPENTANONESHALOCYCLIZATIONHALOGENATION
제목
Electrochemical bromolactonization of alkenoic acids with carbon tetrabromide: Synthesis of bromomethylated gamma-lactones
저자
Kim, Kyeong SeopKim, Dae Young
DOI
10.1080/00397911.2022.2028843
발행일
2022-02-01
유형
Article
저널명
Synthetic Communications
52
3
페이지
402 ~ 412