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Synthesis of beta-selenylated ketones via iodine-mediated selenylation/1,2-carbon migration sequences of alkenyl alcohols
- Kim, Yubin;
- Kim, Dae Young
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25초록
An iodine-mediated selenylation/1,2-carbon migration sequences of alkenyl alcohols is described. This approach provides a mild and operationally simple access to the synthesis of beta-selenated cyclic ketone derivatives from the coupling reaction of alkenyl alcohols with diselenides. (C) 2019 Elsevier Ltd. All rights reserved.
키워드
Selenylation; Iodine-mediated reaction; Semipinacol rearrangement; Alkenyl alcohols; VISIBLE-LIGHT PHOTOREDOX; ASYMMETRIC-SYNTHESIS; SEMIPINACOL REARRANGEMENT; C(SP(3))-H BONDS; RING EXPANSION; C-SE; ACCESS; TETRAHYDROQUINOLINES; DIFUNCTIONALIZATION; FUNCTIONALIZATION
- 제목
- Synthesis of beta-selenylated ketones via iodine-mediated selenylation/1,2-carbon migration sequences of alkenyl alcohols
- 저자
- Kim, Yubin; Kim, Dae Young
- 발행일
- 2019-06-06
- 유형
- Article
- 권
- 60
- 호
- 23
- 페이지
- 1538 ~ 1542
- 언어
- ENG
- 출판사
- Elsevier BV
- 발행국가
- 영국
- 분량
- 5 페이지
- ISSN
- P 0040-4039