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Enantioselective organocatalytic oxidative enamine catalysis-1,5-hydride transfer-cyclization sequences: asymmetric synthesis of tetrahydroquinolines
- Kang, Young Ku;
- Kim, Dae Young
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114초록
The first organocatalytic enantioselective intramolecular oxidative enamine catalysis and 1,5-hydride transfer-ring closure reaction cascade is described. This neutral reaction cascade allows for the efficient formation of ring-fused tetrahydroquinolines with high enantioselectivities.
키워드
유기합성방법론; H BOND FUNCTIONALIZATION; N-BOC-ALDIMINES; MANNICH-TYPE REACTIONS; HYDRIDE TRANSFER; CONJUGATE ADDITION; ROOM-TEMPERATURE; ALPHA,BETA-UNSATURATED KETONES; TRANSFER HYDROGENATION; TERT-AMINOCYCLIZATION; CATALYZED FORMATION
- 제목
- Enantioselective organocatalytic oxidative enamine catalysis-1,5-hydride transfer-cyclization sequences: asymmetric synthesis of tetrahydroquinolines
- 저자
- Kang, Young Ku; Kim, Dae Young
- 발행일
- 2014
- 유형
- Article
- 권
- 50
- 호
- 2
- 페이지
- 222 ~ 224
- 언어
- ENG
- 출판사
- Royal Society of Chemistry
- 발행국가
- 영국
- 분량
- 3 페이지
- ISSN
- E 1364-548X
P 1359-7345