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Synthesis of Ring-Fused 1-Benzazepines via [1,5]-Hydride Shift/7-Endo Cyclization Sequences
- Suh, Chang Won;
- Kwon, Su Jin;
- Kim, Dae Young
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119초록
Synthesis of 1-benzazepines has been achieved via a [1,5] hydride shift/7-endo cyclization sequence. The focus of this research is a direct transformation of 2-(aryl)cyclopropane 1,1-diester derivatives into 1benzazepines using a cyclopropane moiety as the hydride acceptor in internal redox reactions.
키워드
Ring-Fused 1‑Benzazepines; [1; 5]-Hydride Shift/7-Endo Cyclization Sequences; Redox reaction; H BOND FUNCTIONALIZATION; ACTIVE CCR5 ANTAGONISTS; ONE-POT SYNTHESIS; ASYMMETRIC-SYNTHESIS; 1,5-HYDRIDE TRANSFER/CYCLIZATION; HYDRIDE TRANSFER; ENANTIOSELECTIVE FLUORINATION; ORGANOCATALYTIC SYNTHESIS; TERT-AMINOCYCLIZATION; EXPEDITIOUS SYNTHESIS
- 제목
- Synthesis of Ring-Fused 1-Benzazepines via [1,5]-Hydride Shift/7-Endo Cyclization Sequences
- 저자
- Suh, Chang Won; Kwon, Su Jin; Kim, Dae Young
- 발행일
- 2017-03-17
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 19
- 호
- 6
- 페이지
- 1334 ~ 1337
- 언어
- ENG
- 출판사
- American Chemical Society
- 발행국가
- 미국
- 분량
- 4 페이지
- ISSN
- E 1523-7052
P 1523-7060