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Synthesis of selenated gamma-lactones via photoredox-catalyzed selenylation and ring closure of alkenoic acids with diselenides
- Park, Jiwoo;
- Kim, Dae Young
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WEB OF SCIENCE
10Citations
SCOPUS
9초록
A photoredox-catalyzed selenylation and ring closure sequences of alkenoic acid derivatives are achieved. This transformation is efficiently accelerated using an inexpensive Rhodamine 6G as an organophotocatalyst under visible light irradiation. The present method affords efficient and practical access to structurally diverse selenated gamma-lactones in moderate to high yields.
키워드
alkenoic acids; photoredox reaction; selenolactonization; gamma-lactones; ASYMMETRIC-SYNTHESIS; MIGRATION SEQUENCES; QUINOXALIN-2(1H)-ONES; TETRAHYDROQUINOLINES; OXIDATION; EXPANSION; SELENOLACTONIZATION; FUNCTIONALIZATION; CYCLOPENTANONES; ORGANOSELENIUM
- 제목
- Synthesis of selenated gamma-lactones via photoredox-catalyzed selenylation and ring closure of alkenoic acids with diselenides
- 저자
- Park, Jiwoo; Kim, Dae Young
- 발행일
- 2022-07
- 유형
- Article
- 권
- 43
- 호
- 7
- 페이지
- 941 ~ 945