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Enantioselective fluorination of alpha-chloro-beta-keto phosphonates in the presence of chiral palladium complexes
- Woo, Saet Byeol;
- Suh, Chang Won;
- Koh, Kwang Oh;
- Kim, Dae Young
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47초록
The catalytic enantioselective electrophilic fluorination of alpha-chloro-beta-keto phosphonates promoted by chiral palladium complexes has been developed, allowing facile synthesis of the corresponding alpha-chloro-alpha-fluoro-beta-keto phosphonates with excellent enantioselectivity (up to 95% ee). (c) 2013 Elsevier Ltd. All rights reserved.
키워드
Asymmetric catalysis; Chiral palladium catalysts; Electrophilic fluorination; alpha-Chloro-beta-keto phosphonates; MANNICH-TYPE REACTIONS; ASYMMETRIC ELECTROPHILIC FLUORINATION; FRIEDEL-CRAFTS ALKYLATION; CONJUGATE ADDITION; MICHAEL ADDITION; ALPHA,BETA-UNSATURATED KETONES; FUMARATE DERIVATIVES; MEDICINAL CHEMISTRY; CYANO ACETATES; IONIC LIQUID
- 제목
- Enantioselective fluorination of alpha-chloro-beta-keto phosphonates in the presence of chiral palladium complexes
- 저자
- Woo, Saet Byeol; Suh, Chang Won; Koh, Kwang Oh; Kim, Dae Young
- 발행일
- 2013-06-26
- 유형
- Article
- 권
- 54
- 호
- 26
- 페이지
- 3359 ~ 3362
- 언어
- ENG
- 출판사
- Elsevier BV
- 발행국가
- 영국
- 분량
- 4 페이지
- ISSN
- P 0040-4039