Photocatalyst-free photoredox synthesis of diaryl selenides by reaction of diselenides with aryldiazo sulfones

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초록

A photcatalyst-free photoredox synthesis of diaryl selenides has been developed by coupling reaction of diselenides with aryldiazo sulfones. The reaction was accelerated under visible light irradiation without using a photocatalyst or photosensitizer. This approach facilitates the synthesis of diaryl selendes with a wide range of functional group tolerance.

키워드

Aryldiazo sulfonesdiaryl selenidesdiselenidesphotoredox reactionVISIBLE-LIGHT-DRIVENMIGRATION SEQUENCESORGANOSELENIUMARYLATIONEXPANSIONQUINOXALIN-2(1H)-ONESROUTESE
제목
Photocatalyst-free photoredox synthesis of diaryl selenides by reaction of diselenides with aryldiazo sulfones
저자
Jang, JihoonKim, RabinKim, Dae Young
DOI
10.1080/00397911.2020.1850796
발행일
2021-03-04
유형
Article
저널명
Synthetic Communications
51
5
페이지
720 ~ 726