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Visible-light-induced photocatalytic trifluoromethylation/1,2-carbon migration sequences for the synthesis of CF3-substituted cyclic ketones
- Woo, Saet Byeol;
- Kim, Dae Young
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76초록
A visible-light-induced photoredox trifluoromethylation/1,2-carbon migration sequence of alkenols is described. This approach provides a mild and operationally simple access to the synthesis of CF3-substituted cyclic ketones via trifluoromethylation and 1,2-carbon migration of 1-(1-arylvinyl)cyclobutanol derivatives. (C) 2015 Elsevier B.V. All rights reserved.
키워드
Trifluoromethylation; Photocatalysis; Radical reaction; 1,2-Carbon migration; C-H TRIFLUOROMETHYLATION; ONE-POT SYNTHESIS; PHOTOREDOX CATALYSIS; ASYMMETRIC-SYNTHESIS; ALLYLIC ALCOHOLS; COMBINING PHOTOREDOX; HIGHLY EFFICIENT; BOND FORMATION; FLUORINE; ALKENES
- 제목
- Visible-light-induced photocatalytic trifluoromethylation/1,2-carbon migration sequences for the synthesis of CF3-substituted cyclic ketones
- 저자
- Woo, Saet Byeol; Kim, Dae Young
- 발행일
- 2015-10
- 유형
- Article
- 권
- 178
- 페이지
- 214 ~ 218
- 언어
- ENG
- 출판사
- Elsevier BV
- 발행국가
- 스위스
- 분량
- 5 페이지
- ISSN
- E 1873-3328
P 0022-1139