Electrochemical Oxidative Arylsulfonylation and 1,2-Alkyl Shift Sequences of Alkenyl Cyclobutanols for the Synthesis of beta-Sulfonated Cyclopentanones

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WEB OF SCIENCE

17
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SCOPUS

16

초록

A novel process for the synthesis of beta-sulfonated cyclopentanones via electrochemical oxidative radical arylsulfonylation and 1,2-alkyl shift sequences of vinyl cyclobutanols was successfully developed. This approach represents a practical method for the preparation of beta-sulfonated cyclopentanones under environmentally benign reaction conditions.

키워드

Electrochemical oxidation; Sulfonylation; Vinyl cyclobutanols; beta-Sulfonated cyclopentanones; Semipinacol rearrangement; VISIBLE-LIGHT PHOTOREDOX; MIGRATION SEQUENCES; RING EXPANSION; SEMIPINACOL REARRANGEMENTS; ELECTROCATALYTIC APPROACH; DIFUNCTIONALIZATION; QUINOXALIN-2(1H)-ONES; SULFONYLATION; CYCLIZATION; ARYLATION
제목
Electrochemical Oxidative Arylsulfonylation and 1,2-Alkyl Shift Sequences of Alkenyl Cyclobutanols for the Synthesis of beta-Sulfonated Cyclopentanones
저자
Kim, Yebin; Kim, Dae Young
DOI
10.1002/bkcs.12218
발행일
2021-03
유형
Article
저널명
Bulletin of the Korean Chemical Society
권
42
호
3
페이지
510 ~ 513