Visible light-mediated photocatalytic phosphorylation of vinyl azides: A mild synthesis of beta-ketophosphine oxides

초록

The photoredox-catalyzed phosphorylation of vinyl azides is described in this paper. The reaction proceeded smoothly using an inexpensive and easily-accessible Eosin Y as a photocatalyst under mild reaction conditions without any other oxidant, metal, or additive. This synthetic method affords a convenient way to prepare beta-ketophosphine oxides.

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