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Visible light photoredox-catalyzed difluoromethylation and ring expansion of 1-(1-arylvinyl)cyclobutanols
- Kim, Yeon Joo;
- Kim, Dae Young
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50초록
A visible light photoredox-catalyzed difluoromethylation and ring expansion via 1,2-carbon migration of 1-(1-rylvinyl)cyclobutanol derivatives has been developed. This approach offers a facile way to prepare difluoromethyl-substituted cyclopentanone derivatives.
키워드
Difluoromethylation; Photoredox reaction; Radical process; 1,2-Migration; Difluoromethyl-substituted cydopentanones; ONE-POT SYNTHESIS; FLUORINATED SULFONES; ASYMMETRIC-SYNTHESIS; MIGRATION SEQUENCES; TRIFLUOROMETHYLATION; ALKENES; COPPER; DI; CYCLIZATION; OXYDIFLUOROMETHYLATION
- 제목
- Visible light photoredox-catalyzed difluoromethylation and ring expansion of 1-(1-arylvinyl)cyclobutanols
- 저자
- Kim, Yeon Joo; Kim, Dae Young
- 발행일
- 2018-07
- 유형
- Article
- 권
- 211
- 페이지
- 119 ~ 123
- 언어
- ENG
- 출판사
- Elsevier BV
- 발행국가
- 스위스
- 분량
- 5 페이지
- ISSN
- E 1873-3328
P 0022-1139